{"id":45609,"date":"2024-03-21T14:28:15","date_gmt":"2024-03-21T14:28:15","guid":{"rendered":"https:\/\/www.innovationnewsnetwork.com\/?p=45609"},"modified":"2024-03-21T14:28:15","modified_gmt":"2024-03-21T14:28:15","slug":"assembling-safer-and-more-durable-lithium-metal-batteries","status":"publish","type":"post","link":"https:\/\/www.innovationnewsnetwork.com\/assembling-safer-and-more-durable-lithium-metal-batteries\/45609\/","title":{"rendered":"Assembling safer and more durable lithium metal batteries"},"content":{"rendered":"

Lithium metal batteries (LMBs) can provide nearly ten times higher energy density compared to the present lithium-ion batteries (LIBs) and hence are identified as one of the potential future storage systems<\/a>.<\/h2>\n

However, lithium metal batteries pose certain safety concerns and cannot be used for fast-charging applications.<\/p>\n

Uncontrolled dendrite formation, leading to excessive heating and battery short circuits, is one of the critical challenges of its advancement.<\/p>\n

Researchers have previously attempted to address the safety concerns in LMBs but with methods that were laboursome and money\/time intensive.<\/p>\n

Now, T N Narayanan\u2019s lab at the Tata Institute of Fundamental Research, Hyderabad (TIFRH) has reported a simple, scalable, and cost-effective method for assembling a safer and more durable lithium metal battery.<\/p>\n

A paper detailing the research<\/a> was published in the journal Small<\/em>.<\/p>\n

Issues with battery longevity<\/h3>\n

A porous separator membrane lies between the electrodes in a battery, keeping them apart, and is crucial to prevent a short circuit.<\/p>\n

When a lithium metal battery is used for some time, tree-like structures or whiskers called dendrites begin to form on one of the electrodes.<\/p>\n

If these dendrites grow uncontrollably, they may, in some sense, become a physical bridge between the two electrodes, causing a short circuit.<\/p>\n

Suppressing dendrite formation in lithium metal batteries<\/h3>\n

Preeti Yadav and Pallavi Thakur, graduate students and lead authors of the study, used a commonly available graphite derivative powder to modify the separator membrane used in typical lithium metal batteries.<\/p>\n

This modification method entails the deposition of thin coatings of graphitic fluorocarbon (FG) via a large area electrophoretic deposition, where it helps for the formation of a stable LiF and carbon-rich solid electrolyte interface (SEI), aiding a uniform lithium deposition even in higher fluxes.<\/p>\n

It also delivers a high transport number for Li-ion (0.74) compared to the bare CM (0.31), indicating facile Li-ion transport through the membrane. A series of electrochemical, spectroscopic and postmortem analyses provide a mechanistic insight into the role of artificial SEI formation with such membrane modification.<\/p>\n

This modification suppresses dendrite formation and improves the longevity of the battery to a large extent.<\/p>\n

The researchers propose that this method of separator modification holds immense potential to be scaled up for industrial usage.<\/p>\n

However, at a very high current density of 10mA cm2<\/sup>, the battery seems to be deteriorating slowly.<\/p>\n

This could be because of the electroplating of lithium on the carbon (a component of the deposited graphite derivative layer).<\/p>\n

The researchers aim to investigate these challenges further and understand the role of interfaces in improving the performance of a battery from a fundamental standpoint.<\/p>\n","protected":false},"excerpt":{"rendered":"

A new method assesses certain safety concerns and charging applications of lithium metal batteries. Discover more here.<\/p>\n","protected":false},"author":22,"featured_media":45610,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[24204],"tags":[649,24161],"acf":[],"yoast_head":"\nAssembling safer and more durable lithium metal batteries<\/title>\n<meta name=\"description\" content=\"A new method assesses certain safety concerns and charging applications of lithium metal batteries. 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