{"id":44646,"date":"2024-03-01T10:00:44","date_gmt":"2024-03-01T10:00:44","guid":{"rendered":"https:\/\/www.innovationnewsnetwork.com\/?p=44646"},"modified":"2024-03-01T10:00:44","modified_gmt":"2024-03-01T10:00:44","slug":"new-method-to-recycle-rare-earths-from-used-fluorescent-bulbs","status":"publish","type":"post","link":"https:\/\/www.innovationnewsnetwork.com\/new-method-to-recycle-rare-earths-from-used-fluorescent-bulbs\/44646\/","title":{"rendered":"New method to recycle rare earths from used fluorescent bulbs"},"content":{"rendered":"

Discarded fluorescent bulbs have previously been recycled for glass and mercury, but researchers have found that they could also be used to recycle rare earths.<\/h2>\n

Rare earths<\/a>, a group of 17 metals, are not yet widely available and aren\u2019t easily extracted with existing recycling methods, despite their societal importance.<\/p>\n

Now, a team of researchers have discovered a new method to collect slightly magnetic particles from spent fluorescent bulbs that contain rare earths.<\/p>\n

The magnetised chromatography method is detailed in the journal ACS Sustainable Chemistry and Engineering<\/a>. <\/em><\/p>\n

Challenges with rare earth recycling<\/h3>\n

Because of their unique magnetic, electrical, and optical characteristics, rare earths are used in many modern technologies, such as electric vehicles and microchips.<\/p>\n

However, untapped deposits of these metals are rare.<\/p>\n

On top of this, large-scale methods to recycle rare earths from outdated devices are a challenge because the metals are integrated into different components and are only present in small amounts.<\/p>\n

Rare earths in fluorescent bulbs<\/h3>\n

Mixtures of rare earth-based phosphors, the substances that contribute to a light\u2019s colour, are found in a thin coating inside the fluorescent bulb.<\/p>\n

Because of this, the team wanted to develop a low-tech method to easily collect these phosphors. The method would take advantage of the elements\u2019 weak magnetic properties.<\/p>\n

The team utilised a magnetic field<\/h3>\n

In their rare earth recycling method, the researchers used a wire coil to apply a magnetic field to a glass chromatography column filled with stacked disks of stainless-steel mesh. A demonstration sample was then prepared, which was passed through the column to see if it could capture the phosphors.<\/p>\n

The team first obtained three different weakly magnetic rare earth phosphors from a lamp manufacturer. They then mimicked old fluorescent lamp parts by mixing the phosphor particles in a liquid solution with nonmagnetic silica oxide and strongly magnetic iron oxide nanoparticles. These represented glass and metal components in the bulbs.<\/p>\n

When the liquid was injected and flowed through the chromatography column, the phosphors and iron oxide nanoparticles stuck to the magnetised stainless-steel mesh. The water and silica particles flowed out the other end.<\/p>\n

Removing the phosphors<\/h3>\n

The team removed the phosphors from the column by slowly reducing the strength of the external magnetic field while rinsing the column with liquid.<\/p>\n

The magnetic iron oxide nanoparticles were released from the column when the magnetic field was turned off.<\/p>\n

A 93% recovery rate<\/h3>\n

The researchers found that their method recovered 93% of the rare earth phosphors from the initial mixture that mimicked lamp components.<\/p>\n

Although more work is needed to separate individual rare earths from phosphors and to scale the method for industrial recycling applications, the team believe that their approach is a step forward in rare earth recycling for a more sustainable future.<\/p>\n","protected":false},"excerpt":{"rendered":"

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