{"id":34708,"date":"2023-07-11T10:03:48","date_gmt":"2023-07-11T09:03:48","guid":{"rendered":"https:\/\/www.innovationnewsnetwork.com\/?p=34708"},"modified":"2023-07-11T10:03:48","modified_gmt":"2023-07-11T09:03:48","slug":"new-way-make-ammonia-storage-safer-easier","status":"publish","type":"post","link":"https:\/\/www.innovationnewsnetwork.com\/new-way-make-ammonia-storage-safer-easier\/34708\/","title":{"rendered":"New way to make ammonia storage safer and easier"},"content":{"rendered":"

Researchers have discovered a compound that offers a safer and easier way to store ammonia, paving the way for a practical hydrogen economy.<\/h2>\n

Researchers at the RIKEN Center for Emergent Matter Science (CEMS) have found a compound that is set to make ammonia storage safer and easier.<\/p>\n

The discovery, published in the paper \u2018Chemical storage of ammonia through dynamic structural transformation of a hybrid perovskite compound<\/a>,\u2019 also makes it possible for hydrogen to be safely and conveniently stored.<\/p>\n

The result should help pave the way to a decarbonised society with a practical hydrogen economy<\/a>.<\/p>\n

Ammonia\u2019s role as a hydrogen carrier<\/h3>\n

For society to transition to hydrogen-based energy, finding a safe way to store and transport hydrogen is crucial. By itself, the element is highly combustible.<\/p>\n

One hydrogen storage method is storing it as part of another molecule and extracting it as needed.<\/p>\n

Ammonia (NH3<\/sub>) is a good hydrogen carrier because three hydrogen atoms are packed into each molecule. This means that by weight, almost 20% of ammonia is hydrogen.<\/p>\n

What is the current problem with ammonia storage?<\/h3>\n

Ammonia is a highly corrosive gas making it difficult to store and use.<\/p>\n

Current ammonia storage methods involve liquefying it in pressure-resistant containers at temperatures well below freezing.<\/p>\n

Ammonia can also be stored at room temperature and pressure in porous compounds.<\/p>\n

However, storage capacity is low, and the ammonia cannot always be retrieved easily.<\/p>\n

The new ammonia storage method allows easy and complete retrieval<\/h3>\n

The new study reports the discovery of a perovskite, a material with a distinctive repetitive crystal structure. This material is good for ammonia storage as it allows for the easy retrieval of the element at relatively low temperatures.<\/p>\n

The team, led by Masuki Kawamoto at RIKEN CEMS, focused on the perovskite ethylammonium lead iodide (EAPbI3).<\/p>\n

They discovered that at room temperature, its one-dimensional columnar structure undergoes a chemical reaction with ammonia. During this reaction, it dynamically transforms into a two-dimensional layered structure called lead iodide hydroxide (Pb(OH)I).<\/p>\n

Through chemical conversion, ammonia is stored within the layered structure as a nitrogen compound.<\/p>\n

This ammonia storage method is much cheaper than liquefication at -33\u00b0C in pressurised containers.<\/p>\n

Most importantly, the process to retrieve the stored ammonia is just as simple.<\/p>\n

\u201cTo our surprise, ammonia stored in ethylammonium lead iodide could be easily extracted by heating it gently,\u201d said Kawamoto.<\/p>\n

The stored nitrogen compound undergoes a reverse reaction at 50\u00b0C under vacuum and returns to ammonia. This temperature is a lot lower than the 150\u00b0C that is required to extract ammonia from porous compounds.<\/p>\n

The new compound used for ammonia storage is therefore an excellent medium for handling corrosive gases in a simple and cost-effective process.<\/p>\n

Additional bonuses of the new ammonia storage method<\/h3>\n

After returning to the one-dimensional columnar structure, the perovskite can be reused. This allows the ammonia to be repeatedly stored and extracted.<\/p>\n

\"\"
\u00a9 shutterstock\/Niwat panket<\/figcaption><\/figure>\n

As well as this, the normal yellow compound became white after the reaction.<\/p>\n

Kawamoto stated: \u201cThe compound\u2019s ability to change colour when storing ammonia means that colour-based ammonia sensors can be developed to determine the amount of ammonia stored.\u201d<\/p>\n

Future uses for the new storage method<\/h3>\n

The new storage method has a variety of uses.<\/p>\n

In the short-term, the team has developed a safe ammonia storage method that already has multiple uses in society. For example, in fertiliser, pharmaceuticals, and the textiles industry.<\/p>\n

\u201cIn the long-term,\u201d said co-author Yoshihiro Ito of RIKEN CEMS, \u201cwe hope that this simple and efficient method can be a part of the solution for achieving a decarbonised society through the use of ammonia as carbon-free hydrogen carrier.\u201d<\/p>\n

In the future, the research will help achieve the 2016 Sustainable Development Goals set by the UN.<\/p>\n","protected":false},"excerpt":{"rendered":"

Learn about a compound that offers a safer and easier ammonia storage method, paving the way for a practical hydrogen economy.<\/p>\n","protected":false},"author":18,"featured_media":34722,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[24204],"tags":[24413],"acf":[],"yoast_head":"\nNew way to make ammonia storage safer and easier<\/title>\n<meta name=\"description\" content=\"Learn about a compound that offers a safer and easier ammonia storage method, paving the way for a practical hydrogen economy.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" 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