{"id":33913,"date":"2023-06-16T11:29:41","date_gmt":"2023-06-16T10:29:41","guid":{"rendered":"https:\/\/www.innovationnewsnetwork.com\/?p=33913"},"modified":"2023-06-16T11:30:56","modified_gmt":"2023-06-16T10:30:56","slug":"future-demand-magnesium-secondary-batteries-mass-production","status":"publish","type":"post","link":"https:\/\/www.innovationnewsnetwork.com\/future-demand-magnesium-secondary-batteries-mass-production\/33913\/","title":{"rendered":"Securing the future demand for magnesium secondary batteries and their mass production"},"content":{"rendered":"<h2>Increasing the charge and discharge efficiency of magnesium secondary batteries may be key for the energy storage system (ESS) market as the materials for lithium-ion batteries become ever scarcer.<\/h2>\n<p>The demand for lithium-ion batteries is continuing to explode due to the steady increase of electric vehicles and energy storage systems (ESS).<\/p>\n<p>The supply and demand of the raw materials needed for lithium-ion batteries, such as lithium and cobalt, are mostly dependent on specific countries, and thus concerns about securing a stable supply chain are only growing.<\/p>\n<p>With this in mind, researchers are already looking into the <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acsnano.2c08672\" target=\"_blank\" rel=\"noopener\">next-generation secondary batteries.<\/a> Utilising magnesium \u2013 an element abundant in the earth&#8217;s crust could be the answer.<\/p>\n<h3>Magnesium secondary batteries and their potential<\/h3>\n<p>Research led by Dr Minah Lee of the Energy Storage Research Center at the <a href=\"https:\/\/eng.kist.re.kr\/\" target=\"_blank\" rel=\"noopener\">Korea Advanced Institute of Science and Technology (KIST)<\/a> has revealed a chemical activation strategy of magnesium metal that enables the efficient operation of magnesium batteries in common electrolytes that are free of corrosive additives and can be mass-produced.<\/p>\n<p>This new magnesium metal chemical activation process is expected to commercialize magnesium secondary batteries by utilizing non-corrosive general electrolytes.<\/p>\n<p>Magnesium secondary batteries can be expected to have a high energy density because they utilize Mg2+, a divalent ion, instead of monovalent alkali metal ions such as lithium.<\/p>\n<p>The highest energy density can be obtained by directly utilising magnesium metal as an anode, of which volumetric capacity is about 1.9 times higher than lithium metal.<\/p>\n<h3>The challenges of charging and discharging magnesium<\/h3>\n<p>Despite these appealing advantages, difficulties that have hindered its commercialisation arise when looking into the process of charging and discharging.<\/p>\n<p>Efficiently charging and discharging magnesium metal proves difficult due to its reactivity with electrolytes.<\/p>\n<p>The KIST research team have maybe found a solution. Developing a technology to induce a highly efficient charge and discharge reaction of magnesium metal, KIST researchers have opened the possibility of the commercialisation of magnesium secondary batteries.<\/p>\n<p>Unlike previous studies that utilised corrosive electrolytes to facilitate the charging and discharging of magnesium, the researchers used a common electrolyte with a similar composition to existing commercial electrolytes, enabling the use of high-voltage electrodes and minimising the corrosion of battery components.<\/p>\n<h3>Suppressing unwanted reactions within magnesium secondary batteries<\/h3>\n<p>The team synthesised an artificial protective layer, whose composition was based on magnesium alkyl halide oligomers, onto the magnesium surface through dipping.<\/p>\n<p>They found that selecting a specific reaction solvent allowed the formation of nanostructures on the magnesium surface, which in turn allowed the dissolution and deposition of magnesium.<\/p>\n<p>Based on this, the team were able to suppress unwanted reactions with electrolytes and maximised the reaction area through nanostructuring to induce highly efficient magnesium cycling.<\/p>\n<h3>What improvements were seen?<\/h3>\n<p>By applying the developed technology, the overpotential was reduced from more than 2 V to less than 0.2 V when charging and discharging magnesium metal in a common electrolyte without corrosive additives.<\/p>\n<p>The Coulombic efficiency can be increased from less than 10% to more than 99.5%.<\/p>\n<p>The team demonstrated stable charging and discharging of activated magnesium metal in more than 990 cycles,<a href=\"https:\/\/www.innovationnewsnetwork.com\/new-rechargeable-magnesium-battery-demonstrates-excellent-performance\/25740\/\" target=\"_blank\" rel=\"noopener\"> confirming that magnesium rechargeable batteries can operate in conventional electrolytes<\/a> that can be mass-produced.<\/p>\n<blockquote><p>Confirming that magnesium rechargeable batteries can operate in conventional electrolytes that can be mass-produced<\/p><\/blockquote>\n<p>&#8220;This work provides a new direction for the existing magnesium secondary battery research, which has been using corrosive electrolytes that prevent the formation of interfacial layers on magnesium metal surfaces,&#8221; said Dr Minah Lee of KIST.<\/p>\n<p>&#8220;It will increase the possibility of low-cost, high-energy-density magnesium secondary batteries based on common electrolytes suitable for energy storage systems (ESS).\u201c<\/p>\n","protected":false},"excerpt":{"rendered":"<p>The charge and discharge efficiency of magnesium secondary batteries is key for the ESS market as materials for lithium-ion batteries deplete. <\/p>\n","protected":false},"author":24,"featured_media":33920,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[24204],"tags":[24203,24206],"acf":[],"yoast_head":"\n<title>Securing the future demand for magnesium secondary batteries and their mass production<\/title>\n<meta name=\"description\" content=\"The charge and discharge efficiency of magnesium secondary batteries is key for the ESS market as materials for lithium-ion batteries deplete\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.innovationnewsnetwork.com\/future-demand-magnesium-secondary-batteries-mass-production\/33913\/\" \/>\n<meta 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