{"id":18685,"date":"2022-02-23T09:22:16","date_gmt":"2022-02-23T09:22:16","guid":{"rendered":"https:\/\/www.innovationnewsnetwork.com\/?p=18685"},"modified":"2022-08-11T22:13:13","modified_gmt":"2022-08-11T21:13:13","slug":"recycling-co2-possible-novel-method","status":"publish","type":"post","link":"https:\/\/www.innovationnewsnetwork.com\/recycling-co2-possible-novel-method\/18685\/","title":{"rendered":"Recycling CO2 made possible by novel method"},"content":{"rendered":"<h2><span class=\"TextRun SCXW58397991 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"none\"><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">A research team from <\/span><\/span><a class=\"Hyperlink SCXW58397991 BCX0\" href=\"https:\/\/www.global.hokudai.ac.jp\/\" target=\"_blank\" rel=\"noreferrer noopener\"><span class=\"TextRun Underlined SCXW58397991 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"none\"><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-charstyle=\"Hyperlink\">Hokkaido University<\/span><\/span><\/a> <span class=\"TextRun SCXW58397991 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"none\"><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">has <\/span><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">developed a novel method that <\/span><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">could be used for <\/span><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">recycling<\/span><\/span> <span class=\"TextRun SCXW58397991 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"none\"><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">CO<\/span><\/span><sub><span class=\"TextRun SCXW58397991 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"none\"><span class=\"NormalTextRun Subscript SCXW58397991 BCX0\" data-fontsize=\"13\" data-ccp-parastyle=\"heading 2\">2<\/span><\/span><\/sub><span class=\"TextRun SCXW58397991 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"none\"><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">\u202f<\/span><\/span><span class=\"TextRun SCXW58397991 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"none\"><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">waste, <\/span><span class=\"NormalTextRun SCXW58397991 BCX0\" data-ccp-parastyle=\"heading 2\">while also producing molecules useful for drug development.<\/span><\/span><span class=\"EOP SCXW58397991 BCX0\" data-ccp-props=\"{&quot;201341983&quot;:0,&quot;335559738&quot;:40,&quot;335559739&quot;:0,&quot;335559740&quot;:259}\">\u00a0<\/span><\/h2>\n<h3>Why are scientists interested in recycling CO<sub>2<\/sub>?<\/h3>\n<p>In addition to the significant demand for carbon-neutrality, chemists are progressively interested in utilising Carbon Dioxide (CO<sub>2<\/sub>) in syntheses since it is abundant, inexpensive, relatively nontoxic, and <a href=\"https:\/\/www.innovationnewsnetwork.com\/scientists-intend-to-make-electricity-imports-run-on-renewable-energy\/18236\/\">renewable<\/a>.<\/p>\n<p>However, the reactivity of CO<sub>2<\/sub>\u00a0is relatively low. To overcome this, the team led by Professor Tsuyoshi Mita utilised an electrochemical method, where in which an electron is added to either the CO<sub>2<\/sub>\u00a0molecule or to the other molecule in the solution; this makes it far easier for them to react with each other.<\/p>\n<p>This study is considered a breakthrough in the scientific community, as CO<sub>2<\/sub>\u00a0is used to carry out a traditionally difficult type of transformation with unprecedented efficiency. When certain conditions are met, electrons can be shared between many atoms in a molecule by what is called an \u2018aromatic system.\u2019<\/p>\n<p><span class=\"TextRun SCXW266645536 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"auto\"><span class=\"NormalTextRun SCXW266645536 BCX0\">These systems are especially stable and difficult to break, but the new method developed at <\/span><span class=\"NormalTextRun SpellingErrorV2 SCXW266645536 BCX0\">ICReDD<\/span> <span class=\"NormalTextRun AdvancedProofingIssueV2 SCXW266645536 BCX0\">is able to<\/span> <span class=\"NormalTextRun SpellingErrorV2 SCXW266645536 BCX0\">dearomati<\/span><span class=\"NormalTextRun SpellingErrorV2 SCXW266645536 BCX0\">s<\/span><span class=\"NormalTextRun SpellingErrorV2 SCXW266645536 BCX0\">e<\/span><span class=\"NormalTextRun SCXW266645536 BCX0\"> (or break)<\/span><span class=\"NormalTextRun SCXW266645536 BCX0\"> these stable aromatic systems by adding CO<\/span><\/span><sub><span class=\"TextRun SCXW266645536 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"auto\"><span class=\"NormalTextRun Subscript SCXW266645536 BCX0\" data-fontsize=\"11\">2<\/span><\/span><\/sub><span class=\"TextRun SCXW266645536 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"auto\"><span class=\"NormalTextRun SCXW266645536 BCX0\">\u202fto the molecule with the help of electricity. This process has <\/span><span class=\"NormalTextRun SCXW266645536 BCX0\">potential <\/span><span class=\"NormalTextRun SCXW266645536 BCX0\">applications <\/span><span class=\"NormalTextRun SCXW266645536 BCX0\">in <\/span><span class=\"NormalTextRun SCXW266645536 BCX0\">recycl<\/span><span class=\"NormalTextRun SCXW266645536 BCX0\">ing<\/span> <span class=\"NormalTextRun SCXW266645536 BCX0\">CO<\/span><\/span><sub><span class=\"TextRun SCXW266645536 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"auto\"><span class=\"NormalTextRun Subscript SCXW266645536 BCX0\" data-fontsize=\"11\">2<\/span><\/span><\/sub><span class=\"TextRun SCXW266645536 BCX0\" lang=\"EN-GB\" xml:lang=\"EN-GB\" data-contrast=\"auto\"><span class=\"NormalTextRun SCXW266645536 BCX0\">\u00a0and<\/span> <span class=\"NormalTextRun SCXW266645536 BCX0\">producing high value-added dicarboxylic acids from simple starting materials, <\/span><span class=\"NormalTextRun SCXW266645536 BCX0\">which essentially <\/span><span class=\"NormalTextRun SCXW266645536 BCX0\">solv<\/span><span class=\"NormalTextRun SCXW266645536 BCX0\">es<\/span><span class=\"NormalTextRun SCXW266645536 BCX0\"> two problems at once.<\/span><\/span><\/p>\n<h3>How was this reaction made possible?<\/h3>\n<p>Prior to the experiments, ICReDD scientists screened various heteroaromatic compounds by calculating their reduction potentials, which is a measure of how a compound will react when subjected to an electric environment.<\/p>\n<p>The results enabled researchers to identify potentially reactive compounds and carry out targeted electrochemical experiments. This demonstrated that a wide variety of substrates that exhibit highly negative reduction potentials can very efficiently undergo this unprecedented dearomative addition of two CO<sub>2<\/sub>\u00a0molecules.<\/p>\n<p>Therefore, the obtained dicarboxylic acids can be easily and cost-effectively modified into key intermediates for biologically active compounds, which could lead to more efficient and economical drug development.<\/p>\n<p>Researchers involved in this study attributed the rapid development of this new process to their strategy of primarily performing computational analyses that informed their experimental choices in the lab.<\/p>\n<p>\u201cI started to learn computational chemistry when I joined ICReDD. Within one year, I was able to utilise advanced calculation techniques, which was very useful for guiding my decisions in the lab,\u201d noted first author, Dr Yong You.<\/p>\n<p>\u201cIt took only eight months to complete the research and publish the paper, which is much faster than a conventional project involving experiments. Significant research time is saved because a computer can reliably predict the feasibility of the reactant structures and possible reaction pathways\u201d concluded Tsuyoshi Mita, leader of the project.<\/p>\n<p>This study was conducted at the Institute for Chemical Reaction Design and Discovery (ICReDD) in Hokkaido University.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>A research team from Hokkaido University has developed a novel method that could be used for recycling CO2\u202fwaste, while also producing molecules useful for drug development.\u00a0 Why are scientists interested in recycling CO2? In addition to the significant demand for carbon-neutrality, chemists are progressively interested in utilising Carbon Dioxide (CO2) in syntheses since it is [&hellip;]<\/p>\n","protected":false},"author":21,"featured_media":18686,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[24429],"tags":[3478,763],"acf":[],"yoast_head":"\n<title>Recycling CO2 made possible by novel method<\/title>\n<meta name=\"description\" content=\"A research team has developed a novel method that could be used for recycling CO2\u202fwaste, while producing molecules for drug development.\" \/>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" 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